多功能橡胶助剂HT918在载重子午线轮胎胎面胶中的应用

研究多功能橡胶助剂HT918在载重子午线轮胎胎面胶中的应用。结果表明:在胎面胶中加入多功能橡胶助剂HT918,胶料的t10和t90缩短,交联密度增大,抗硫化返原性提高;硫化胶的定伸应力和拉伸强度增大,拉断伸长率和撕裂强度减小,耐老化性能、耐屈挠性能和耐磨性能提高,压缩生热降低;轮胎的抗湿滑性能和耐久性能提高,滚动阻力降低;多功能橡胶助剂HT918的综合性能等同或优于国外同类产品。     

Synthesis and XPS investigation of superdense lithium-graphite intercalation compound, LiC2

The superdense lithium-graphite intercalation compound (GIC),LiC₂, first synthesized by the author was prepared by the original technique in a piston-cylinder high-pressure chamber with internal heater. Cleaved surfaces of this compound, LiC₃, LiC₆ and pristine graphite were studied by the X-ray photoelectron spectroscopy (XPS) technique. It was shown that chemical shifts of carbon do not vary in the range LiC₆ to LiC₂ which suggests that the additional lithium intercalation into LiC₆ gives no significant change in the charge transfer rate per carbon atom. Carbon/lithium atom ratios were obtained for freshly cleaved surfaces and for the surfaces after argon ion bombardment. It was shown that the bombardment results in the surface decomposition of LiC₂-GIC.     

复合变质处理对铸造热锻模具钢力学性能的影响

研究了变质处理对铸造热锻模具钢力学性能的影响。结果表明：在相同热处理条件下，经RE和RE—Nb复合变质处理后，其冲击韧性与变质处理前相比分别提高了9．7和14．5J／cm^2，常温抗拉强度σb分别提高了82和234MPa，高温抗拉强度分别达到了976和994MPa，而硬度变化不大。     

MICROSTRUCTURE OF RAPIDLY SOLIDIFIED TiAl ALLOY POWDER

The rapidly solidified powder of Ti-34Al-2Mn alloy was obtained by means of ultrasonicgas atomisation (USGA) technique.The tupical size of the powder is 27 μm.X-ray diffractionresults show that the powder consists of major α_2-phase and minor γ-phase.Under opticalmicroscope both equiaxed and dendritical microstructure features were observed on RS pow-der sections.After annealing at 900 ℃/for 2 h in vacuum,most of α_2-phase transforms intoγ-phase,resulting in refinement of structure.     

BEHAVIOR OF Mg AND ITS EFFECT ON MECHANICAL PROPERTIES OF CAST Fe_3Al ALLOYS

Proper addition of 0.002 wt-% Mg to cast Fe_3Al alloy may obviously improve the room andhigh temperature tensile properties.Auger spectra show that Mg segregates near grainboundaries as very thin layers.Observation under TEM reveals that a suitable amount of Mgenhances ability of cooperative internal deformation so that the dislocations will ease the con-tinuous slip deformation through grain boundaries.The fracture feature of Fe_3Al alloy is oftransgranular cleavage at room temperature and cracks initiate at grain boundaries.     

硼对快凝Ni3Al组织结构及力学性能的影响

本文通过快凝及加硼合金化的方法改善金属间化合物Ni_3Al的韧性。实验表明:加入0.5-1.4at.-％的硼对Ni_3Al的塑性提高最有利。结构分析表明:在含1.37at.-％硼的Ni_3Al中,硼以Ni_(23)B_6弥散相及晶界偏聚方式存在;当硼量增至2.22at.-％时,硼以粗大的Ni_(23)B_6及NiB_(12)相在晶界处析出。无硼的Ni_3Al晶界为大角度晶界;当硼加至1.37at.-％时,Ni_3Al晶界以位错排列成亚晶界,以小角晶界形式存在。     

添加Ce与P+Sr复合变质对高硅耐热铝合金组织与性能的影响

研究了添加Ce与P＋Sr复合变质对Al-21Si-1.5Cu-0.5Mg-2.5Fe合金显微组织与性能的影响.结果表明：添加1.5?使粗大针状铁相消失,形成富Ce富Fe的鱼骨状相;P＋Sr复合变质可使初晶硅平均尺寸由70mm细化到20mm,共晶硅平均截线长降到2.1 mm,合金室温抗拉强度比未变质前提高21.5%,与P＋Sr＋Ce复合变质的Al-21Si-1.5 Cu-1.5Ni-2.5Fe-0.5Mg合金相当.     

化合物TbMn6Sn6的磁性和磁相变

采用分子场理论模型对稀土-过渡族金属间化合物的磁性、自旋重取向相变和场诱导的一级磁相变进行了研究.从理论上计算了TbMn6Sn6的易磁化方向随温度的变化以及不同温度时的磁化曲线,描述了自旋重取向相变和场诱导的一级磁相变.基于单离子模型计算了Tb离子和化合物的一阶和二阶磁晶各向异性常数及其随温度的变化,得到了和实验数据基本一致的结果.结果表明:Mn次晶格和Tb次晶格磁晶各向异性能之间的相互竞争是导致自旋重取向相变的物理机制,而稀土离子的四阶晶场项对场诱导的一级磁相变产生很大的影响.     

提高电火花加工效率的一种方式

基于离子在电磁场下快速而有规律运动的原理。提出了提高电火花加工效率的一种新策略，一个简单的采用功率场效应晶体管的主电路及它们的逻辑驱动信号也同时在文中提出了和分析。     

各种介质对等径三通管复合胀形工艺的影响

三通管广泛应用于工业、建筑、装饰等行业,为了提高三通管的质量及降低加工成本,三通管胀形工艺研究势在必行.胀形工艺关键技术之一是胀形介质的选用,通过采用石蜡、粘土、尼龙、硅橡胶和聚氨酯橡胶等材料作为胀形介质进行了大量的胀形实验.从实验中得出的数据可知,以上各种介质都可以达到要求的胀形系数.但从得到零件的外部及内部的质量来看,并且结合金属流动规律分析得知,内壁要求高的工件,可选用尼龙、聚氨酯橡胶、硅橡胶为介质;反之,对内壁要求不高或无要求的工件,可用石蜡作为介质,并且可回收利用,降低成本.这对于三通管胀形技术的实际生产具有重要的指导意义.